Indicate the types of isomerism exhibited by the following complexes and draw the structures for these isomers:
$(i)$ $K[Cr(H_2O)_2(C_2O_4)_2]$
$(ii)$ $[Co(en)_3]Cl_3$
$(iii)$ $[Co(NH_3)_5(NO_2)](NO_3)_2$
$(iv)$ $[Pt(NH_3)(H_2O)Cl_2]$

Vedclass pdf generator app on play store
Vedclass iOS app on app store
(N/A) $(i)$ $K[Cr(H_2O)_2(C_2O_4)_2]$ exhibits geometrical isomerism (cis and trans forms) and optical isomerism (the cis-isomer is optically active).
$(ii)$ $[Co(en)_3]Cl_3$ exhibits optical isomerism due to the presence of the bidentate ligand $en$ (ethylenediamine),forming non-superimposable mirror images (d and l forms).
$(iii)$ $[Co(NH_3)_5(NO_2)](NO_3)_2$ exhibits linkage isomerism because the $NO_2^-$ ligand can coordinate through either the $N$ atom or the $O$ atom $(ONO^-)$,and ionization isomerism due to the exchange of $NO_2^-$ and $NO_3^-$ ions.
$(iv)$ $[Pt(NH_3)(H_2O)Cl_2]$ exhibits geometrical isomerism (cis and trans forms) due to the square planar geometry of the $Pt(II)$ complex.

Explore More

Similar Questions

How many isomeric forms are possible for the ion $[CO(NH_3)_4Cl_2]^{+}$?

Which of the following pairs of complexes have the same magnetic moment,same hybridisation,and same $EAN$ value?

In a particular isomer of $[Co(NH_3)_4Cl_2]^0$,the $Cl-Co-Cl$ angle is $90^\circ$. This isomer is known as:

The total possible coordination isomers for the following compounds respectively are :
$[Co(en)_3] [Cr(C_2O_4)_3]$
$[Cu(NH_3)_4] [CuCl_4]$
$[Ni(en)_3] [Co(NO_2)_6]$

For a tetrahedral complex $[MCl_{4}]^{2-}$,the spin-only magnetic moment is $3.83 \ BM$. The element $M$ is

Vedclass Products

For Students

Vedclass Test Series

Mock tests in real JEE/NEET style with performance analysis. 5-day free trial.

Start Free Trial
For Teachers

Exam Paper Generator

Generate Set A/B/C/D exam papers from 7.5L+ questions in 2 minutes. 3 chapters free.

Try Free
For Institutes

Online Exam Module

Live online exams with unlimited students, 360° analytics & white-label branding.

See Demo